Reductive alkylation of illinois No. 6 coal. 1H and 13C n.m.r. spectra of the 13C-enriched alkylation products

The reductive alkylation of Illinois No. 6 coal has been carried out using potassium and naphthalene in tetrahydrofuran and methyl-¹³C and butyl-1 -¹³C iodides to alkylate the resultant polyanion. The soluble products of the reductive alkylation reaction were isolated by extraction and chromatography. Proton and carbon n.m.r. spectra were recorded. The intense resonance signal at δ3.95 which appears in the proton n.m.r. spectra of Illinois No. 6 coal butylated with unenriched butyl iodide is split into a doublet by the ¹³C nuclei. Similar results were obtained for the methylation products. The chemical shift and coupling interaction establish that aryl ethers are a very important constituent of the alkylated coal. The carbon n.m.r. spectra of the coal alkylated with ¹³C-enriched alkyl iodides are intense. The resonances of the C-alkylation products appear in a single broad band with a maximum intensity in spectral regions compatible with the formation of the reductive alkylation products of certain polynuclear aromatic hydrocarbons or the base-catalysed alkylation of certain benzylic carbon atoms. The resonances of the N -alkylation products appear in two distinct bands. These resonances are tentatively assigned to amines produced as a result of reductive alkylation of heterocyclic compounds. The resonances of the 0-alkylation products appear in three distinct bands which can be assigned to alkyl aryl ethers, alkyl aryl ethers with substituents at the adjacent positions, and to alkyl carboxylates. The ratio of ethers to carboxylates in the soluble alkylation products was determined to be 7.8 for butylation and 8.0 for methylation. The Chromatographic fractions contain different amounts of C-, N-, and 0-alkylation products. This finding suggests that the coal structure is not highly uniform.     

[火用]分析环境模型及其确立原则的研究

对现有的环境模型和有关环境模型的理论进行了评述和分析，指出了确定环境模型的理论以及现有的环境模型中存在的问题，提出了比较系统的确定环境模型的理论原则。     

浅析无线网现状及相关技术

无线网作为一种现代化的技术手段,随着网络信息技术的不断发展完善,在实际中的应用越来越广泛和普遍,对于无线网技术的研究与关注内容也越来越多,进行无线网现状以及相关技术的研究分析,有利于促进无线网在实际应用中的改进和提升,具有积极的作用和意义。下文将结合无线网在实际网络通信传输中的应用现状,以网络建设中的安全管理为例,对其安全保护现状以及存在的问题、解决措施等进行分析论述。     

新一代天气雷达发射机故障诊断分析

我省的新一代天气雷达在多年的运行过程中出现了各种不同类型的故障,有些严重故障直接导致雷达停机,影响了气象预报服务.本文介绍和总结了该雷达发射机部分出现的一些主要故障,这些故障都集中在雷达射频驱动器、聚焦线圈电源、触发器、调制器、后充电调整器等组件上.通过对这些组件的功能和工作原理的分析,详细介绍发射机故障诊断分析的关键技术.     

语音识别中小波分析的应用

语音信号是一种时变、非平稳的随机信号。现有语音识别系统的适应性比较差,尤其在高噪声环境下的语音识别非常困难,若将语音识别系统商品化,还有识别速度、拒识问题以及关键词／句检测技术等细节问题需要解决。如何把语言学、生理学、心理学方面的研究成果量化、建模并用于语音识别,还需深入研究。本文介绍了语音识别中小波分析的研究现状及几种常见的技术方法,并且分析探讨了语音识别中小波分析的应用和发展前景。     

Response surface methodology study on electrochemical adsorption regeneration of water-based drilling fluid waste

ABSTRACT

This study explores an electrochemical adsorption method on the regeneration of aqueous drilling fluid waste. Response surface analysis was applied to investigating the electrochemical factors on the adsorption performance. The response surface polynomial model optimized the preferred electrochemical adsorption conditions with adsorption time of 20 min, spacing electrodes of 5 cm, adsorption concentration of 5% and NaCl concentration of 2 g/L. The model calculated electrochemical adsorption amount of drilling fluid showed only 1.3% deviation from the experimental results. Thus, the model could provide effective support for the device design and application of drilling fluid electrochemical adsorption process.     

乙烯分离技术分析

从技术先进性、能耗、流程复杂性和运行稳定性等诸多方面对占据乙烯市场的三大分离技术进行了分析。并认为用户在选择分离技术时应综合考虑各方面因素，把握重点，选择出适合的技术。     

Measurement of zeolite,silicate, and phosphate in laundry detergent products by inductively coupled plasma atomic emission spectrometry

This paper reports the development of a method for simultaneously measuring zeolite, silicate, and phosphate in laundry detergent products by inductively coupled plasma atomic emission spectrometry. A sample is decomposed under alkaline oxidative conditions to decompose zeolite, silicate, phosphate, and organic substances. Then hydrochloric acid is added to the decomposed solution to dissolve aluminum hydroxide precipitate before analysis. This sample preparation procedure was investigated by using a total organic carbon analyzer and was confirmed to be applicable to simultaneous measurements of zeolite, silicate, and phosphate. Relative standard deviation for the analysis is less than 2.1%, recovery is more than 99.0%, and the calibration curve gives a correlation coefficient ofR=1.000. The detection limit of this method for aluminum and silicon is 0.1%, and for phosphorus, 0.2% by weight in the product. This method is applicable to various laundry detergent products that contain zeolite, silicate, or phosphate and is five times faster than the three wet chemical methods.     

基于Moldflow CAE和UG/CAD的进气罩模具设计

运用CAE分析和CAD设计相结合的方法,设计了某塑件的四面抽芯直接浇口两板模注塑模具。针对塑件浇注困难的问题,在4种潜在浇注方案的基础上,优先选用直浇方案。运用CAE辅助分析找出最佳浇口位置,然后,针对该方案的流动,做了充填、保压、冷却及翘曲方面的优化,经调整后获得了较优的浇注方案。CAE分析结果表明,运用CAD获得了模腔的分型设计及侧抽芯成型件设计。模具结构为单次分型,开模时,四面滑块同步抽芯,塑件的脱模采用顶针+顶块共同顶出方式,有利于型芯水路的开设,减少塑件的顶出变形,保证塑件的成型质量。综合运用CAE/CAD进行模具结构设计,能够缩短新塑件与模具的开发周期与费用,带来了良好的经济效益,提高企业的市场竞争力。     

合成法生产氢溴酸技术经济论证

介绍了合成法制取氢溴酸系列产品的工艺路线和技术指标，对１０００ｔ／ａ和３００ｔ／ａ生产线进行了技术经济分析。